一.团队简介
团队立足农业环境保护和环境污染控制领域国际前沿,面向国家需求,紧扣我国农业生产与农村生态环境面临的重大课题,依托“湖南省环境保护畜禽养殖与农业种植污染控制工程技术中心”、“湖南省农业典型污染物生态修复与实地保护国际科技合作基地”、“湖南省农村生活污水处理处置工程研究中心”等省部级科研与教学平台,开展农业与农村流域水土污染治理与修复、环境材料与废物资源化、环境污染物及检测技术、环境污染物生态毒理学等方面的科研与教学、技术推广工作。
团队近5年来,团队先后承担了50余项国家级省部级研究课题,获资助1800余万元,在国内外期刊发表研究论文150余篇,获得专利10余项,省部级奖励2项,主持或参与编制国家级和团体标准/行业标准4项。
二.团队人员
团队现有固定成员14人,包括教授4人,副教授7人,其中湖南省委组织部“青年百人”计划1人,“香江学者”1人,国家博士后创新人才1人,湖南省省青年骨干教师2人、湖南农业大学“1515”人才学术骨干2人、湖南农业大学神农学者青年英才Ⅰ层次人才5人,现有博士后、博士、硕士研究生近30人。
序号 |
姓名 |
学历 |
职称 |
从事方向 |
1 |
罗琳 |
博士 |
教授 |
固体废物资源化、重金属污染土壤与水体修复 |
2 |
颜智勇 |
博士 |
教授 |
农村和工业污水处理及装备化 |
3 |
吴根义 |
博士 |
教授 |
农业面源污染防治、畜禽养殖污染防治与管理 |
4 |
秦普丰 |
博士 |
教授 |
重金属污染场地修复和污水处理处置 |
5 |
颜丙花 |
博士 |
教授 |
固体废物资源化、厌氧膜生物反应 |
6 |
张嘉超 |
博士 |
教授 |
固体废物资源化、重金属物污染土壤修复 |
7 |
周耀渝 |
博士 |
教授 |
典型农业区土壤及地下水污染修复 |
8 |
罗惠莉 |
博士 |
副教授 |
重金属污染农田修复、农药残留检测 |
9 |
黄红丽 |
博士 |
副教授 |
固体废物资源化、重金属物污染水体与土壤修复 |
10 |
戴春皓 |
博士 |
副教授 |
区域大气污染物防治 |
11 |
罗双 |
博士 |
副教授 |
有机污染物治理、环境模型、复杂废水处理 |
12 |
谢先德 |
博士 |
副教授 |
重金属污染修复与治理 |
13 |
曹林英 |
博士 |
副教授 |
环境毒理学与评价 |
14 |
张立华 |
博士 |
副教授 |
固体废物资源化、环境微生物 |
15 |
杨建 |
博士 |
副教授 |
环境安全学、环境污染风险评估 |
16 |
邓娜 |
博士 |
讲师 |
流域与区域污染修复与规划 |
17 |
杨远 |
博士 |
讲师 |
分析化学与纳米颗粒 |
18 |
彭慧 |
博士 |
讲师 |
湿地污染物治理与修复 |
19 |
智丹 |
博士 |
讲师 |
环境功能材料与应用 |
三.主要研究方向
1. 矿山酸性废水被动式处理技术与推广
为解决铁离子在被动式处理系统中造成的堵塞问题、锰离子在系统中难去除的问题,提出了铁锰氧化-硫酸盐还原的技术路线。前端铁锰氧化采用由湖南农业大学筛选驯化的铁锰氧化菌,利用生物固锰除锰理论,将铁锰氧化菌与材料进行组配,应用生物扩培技术,进行接种。该菌能在酸性条件下对铁锰重金属离子进行氧化,形成生物锰氧化物。末端应用硫酸盐还原生物滤池,通过异化SO42-为电子受体将其还原,它能把硫酸盐、亚硫酸盐、硫代硫酸盐、单硫还原为硫化物,在处理富含硫酸盐和金属离子的废水具有较强的能力,利用SRB可以同时去除废水中硫酸根和金属离子,从而达到以废治废的目的。
新型污染物控制技术的研发和推广是环境工程重要的研究方向,系统开展了基于铁锰新材料和新工艺的研发与推广,通过对现有铁锰材料的定向修饰和基于铁锰氧化还原工艺的改良,针对性的用于新型环境污染物的处理,为污染物的控制提供切实可行的技术方案。
2. 农业源新型污染物的环境归趋及风险评价
主要开展农业源新型污染物在环境中的迁移、转化、归趋、及其对生态系统各要素的影响,包括水解、氧化降解、光降解、生物降解、降解产物毒性、污染物在环境介质中的累积、污染物对生态系统各要素的毒性;利用模拟实验和污染物结构与性质/活性定量关系(QSAR)模型计算等研究方法,预测污染物在环境中的迁移、归趋和毒性,为农业源化学品的风险评价和管理提供数据支撑。
3. 环境健康与污染物生态毒理
新兴有机污染物内分泌干扰效应及分子机制:从分子、细胞、动物活体以及理论模拟计算等多个层面,系统研究新兴污染物通过干扰内分泌系统对人体健康的危害作用,包括生殖发育毒性、激素相关癌症以及糖尿病和肥胖等代谢相关疾病,并探究污染物毒害作用的分子起始事件和毒性通路以及污染物的结构-效应关系。
纳米毒理及联合毒性:主要研究纳米塑料、金属纳米材料、纳米农药等的细胞毒性及分子机制,与典型污染物联合暴露的生物效应及作用机制。
微污染物复合生态毒理:通过不同营养级生物的生态毒理评价方法和基于细胞关键毒性通路的体外高通量诊断技术,评价实际环境介质中微污染物的复合生态毒性及毒理机制。
4. 基于种养平衡调控的农林有机固废定向化学生物转化及应用
开展基于种养平衡调控的农林废弃物定向化学生物转化机制研究,实现农林废弃物碳氮磷等关键元素的平衡和资源化利用,对于提高废弃物资源化利用效率和价值和推动湖南农业绿色可持续发展具有重要的现实意义。
项目团队根据湖南区域种养高度分离和集约化水平较低的特点,通过秸秆制生物炭解决其利用中储存、运输难的问题,突破生物炭调控秸秆与畜禽粪污共堆肥过程碳氮元素释放的技术瓶颈,结合厌氧产沼和堆肥化等相关技术的元素转化规律和生物学机制的深入研究,系统阐释农林废弃物定向化学生物处置的效率与机制,掌握化学生物处理处置过程中抗生素及残留农药等毒害物质的转化与减控机理,实现碳氮磷元素平衡的农林废弃物全量、高价资源化利用。
四.承担的主要科研项目
[1] 国家重点研发计划项目,2016YFC0403000,重金属废水深度处理与安全利用技术集成示范及转化模式,2016.09-2019.08,主持人:罗琳
[2] 国家自然科学基金青年项目,2190605,基于雌激素膜受体GPER探究新烟碱农药对乳腺癌增殖转移的影响及分子机制,2020.01-2022.12,主持人:曹林英
[3] 国家自然科学基金青年项目,UV活化亚硫酸盐/过硫酸盐协同矿化难降解有机污染物的机理及模型研究,2019.01-2021.12,主持人:罗双
[4] 国家自然科学基金青年项目,21806170,厌氧发酵集成离子置换型电渗析强化挥发性脂肪酸代谢和CO2回用的效能与机制研究,2019.01-2021.12,主持人:颜丙花
[5] 国家自然科学基金青年基金,21806003,洛克沙胂在针铁矿/水界面的光化学转化行为及机理研究,2019.01-2021.12,主持人:谢先德
[6] 国家自然科学基金青年项目,51709103,杂化多孔碳纳米铁微囊修复地下水中芳香族有机砷污染的效能及机理研,2018.01-2020.12,主持人:周耀渝
[7] 国家自然科学基金青年项目,51408219,农业废物堆肥氨氧化细菌(AOB)和古菌(AOA)对基质微环境变化的响应特征及驱动氨氧化的关键因子分析,2015.01-2017.12,主持人:张嘉超
[8] 国家自然科学基金青年项目,51108178,禽畜粪便堆肥对印度芥菜修复重金属污染土壤中铜锌迁移转化的影响,2012.01-2014.12,主持人:黄红丽
[9] 国家博士后创新人才支持计划,BX20200127,以小型猪为模型研究抗菌剂三氯卡班诱导脂代谢异常和肥胖的分子机制,2021.01-2022.12,主持人:曹林英
[10] 第二次全国污染源普查农业行业普查数据宏观质量校核技术方案编制,2018.12-2019.12,主持人:吴根义
[11] 中国博士后科学基金面上项目,2017M620507,典型苯胂酸类化合物在铁锰氧化物上的吸附解吸机理研究,2017.10-2019.3,主持人:谢先德
[12] 中国博士后基金,典型金属纳米颗粒在水-水稻体系中迁移转化及毒性研究,2019年-2021年,No. 2019M652768,主持人:杨远
[13] 湖南省自然科学基金青年项目,2020JJ5222,新烟碱农药通过雌激素膜受体GPER介导的雌激素干扰分子机制研究,2021.01-2022.12,主持人:曹林英
[14] 湖南省自然科学基金,水-水稻体系中铂纳米颗粒迁移转化及纳米毒性研究, 2020年-2022年,No.2020JJ5227,主持人:杨远
[15] 湖南省自然科学基金项目,农业废物堆肥化过程中酒糟及其生物炭添加的N2O减排特征及微生物学机制,2020/04-2023/03,主持人:张嘉超
[16] 湖南省重点研发项目,2019SK2281,入河水体重金属污染阻控与锑微污染深度净化关键技术,2019.07-2021.06,课题负责人:罗双
[17] 湖南省自然科学基金,湘自科2018JJ3240,农业面源区域氨基污染源对大气细颗粒物贡献率及转化机理研究,2018.01-2020.12,主持人:戴春皓
[18] 湖南省重点研发计划项目,2018SK2022,高浓度含铊废水高效处理技术及集成装备研发,2018.01-2020.12,主持人:黄红丽
[19] 湖南省重点研发项目,湿式氧化调理污泥多元复配制备砷污染土壤专用修复剂技术及示范,2017.09-2020.08,课题负责人:张嘉超
[20] 湖南省重点研发项目,2016WK2010,典型农药污染物在水环境中的痕量快速检测及强化去除技术集成与示范,2016.09-2018.08,主持人:张嘉超
[21] 湖南省科技计划项目,2015WK3016,湘江流域重金属矿山酸性废水的耐受微生物种群的筛选及其生物固定化处理技术,2016.01-2018.12,主持人:罗琳
[22] 湖南省自然科学基金,高级还原-高级氧化协同矿化新型含氯有机农药的机理及预测模型研究,2019.01-2021.12,在研,主持人:罗双
[23] 山东省自然科学基金项目,ZR2016BB06, 电膜原位分离促进餐厨垃圾与剩余污泥高固厌氧共消化产脂肪酸的应用研究,2016.11-2018.08, 主持人:颜丙花
[24] 湖南省重点研发计划,稻田重金属污染修复的新型硅肥技术引进创新与示范,2019.01-2021.12,2019KW2031,课题负责人:杨远
五.发表学术论文
[1] Dongmei Hou, Pan Zhang, Jiachao Zhang, Yaoyu Zhou, Yuan Yang, Qiming Mao, Daniel C.W. Tsang, Avelino Núñez-Delgado, Lin Luo∗. Spatial variation of sediment bacterial community in an acid mine drainage contaminated area and surrounding river basin. Journal of Environmental Management, 2019, 251:109542.
[2] Qiming Mao, Yaoyu Zhou, Yuan Yang, Jiachao Zhang, Lifen Liang, Hailong Wang, Shuang Luo⁎, Lin Luo⁎, Paramsothy Jeyakumar, Yong Sik Ok, Muhammad Rizwan. Experimental and theoretical aspects of biochar-supported nanoscale zero-valent iron activating H2O2 for ciprofloxacin removal from aqueous solution. Journal of Hazardous Materials, 2019, 380:120848.
[3] Dongmei Hou, Pan Zhang, Dongning Wei, Jiachao Zhang, Binghua Yan, Linying Cao, Yaoyu Zhou*, Lin Luo*. Performance and microbial community profiles in pilot-scale biofilter for the simultaneous removal of ammonia, iron and manganese at different manganese concentrations. Bioprocess and Biosystems Engineering, 2019, 42(5):741-752.
[4] Danxing Yang, Xiaocheng Liu, Yaoyu Zhou*, Lin Luo*, Jiachao Zhang, Anqi Huang, Qiming Mao, Xiao Chen, Lin Tang. Aptamer-based biosensors for detection of lead(II) ion: a review, Analytical methods, 2017,9(13): 1976-1990.
[5] Rui Zhou, Xiaochen Liu, Lin Luo*, Yaoyu Zhou*, Jianhong Wei, Anwei Chen, Lin Tang, Haipeng Wu, Yaocheng Deng, Fengfeng Zhang, Yangyang Wang. Remediation of Cu, Pb, Zn and Cd-contaminated agricultural soil using a combined red mud and compost amendment, International Biodeterioration & Biodegradation, 2017, 118:73-81.
[6] Cao Lin-Ying, Ren Xiao-Min*, Yang Yu, et al. Hydroxylated polybrominated biphenyl ethers exert estrogenic effects via nongenomic G protein-coupled estrogen receptor mediated pathways. Environmental Health Perspectives, 2018, 126 (5), 057005.
[7] Cao Lin-Ying, Zheng Zi-Ye., Ren Xiao-Min, et al. Structure-dependent activity of polybrominated diphenyl ethers and their hydroxylated metabolites on estrogen related receptor γ: in vitro and in silico study. Environmental Science & Technology, 2018, 52 (15), 8894–8902.
[8] Cao Lin-Ying, Ren Xiao-Min*, Li Chuan-Hai, et al. Bisphenol AF and bisphenol B exert higher estrogenic effects than bisphenol A via G protein coupled estrogen receptor pathway, Environmental Science & Technology, 2017, 51 (19), 11423-11430.
[9] Cao Lin-Ying, Ren Xiao-Min*, Li Chuan-Hai, et al. Organophosphate esters bind to and inhibit estrogen-related receptor γ in cells. Environmental Science & Technology Letters, 2018, 5(2), 68-73.
[10] Lin-Ying Cao*, Yun-Hao Xu, Sen He, et al. Antimicrobial triclocarban exhibits higher agonistic activity on estrogen-related receptor γ than triclosan at human exposure levels: a novel estrogenic disruption mechanism. Environmental Science & Technology Letters, 2020, 2020, 7 (6): 434-439.
[11] Dai C., Qin P. Wang Z. et al. Mercury enrichment in Brassica napusin response to elevated atmospheric mercury concentrations. Frontiers of Environmental Science & Engineering, 2017, 11(1):1-8.
[12] Dai C., Zhou Y., Peng H., et al. Current progress in remediation of chlorinated volatile organic compounds: a review. Journal of Industrial and Engineering Chemistry, 2018,106-119.
[13] Dai C., Huang S., Zhou Y., et al. Concentrations and emissions of particulate matter and ammonia from extensive livestock farm in South China. Environmental Science and Pollution Research, 2018, 26.1871-1879.
[14] Dai C., Huang S, Peng H., et al. Particulate pollution status and its characteristics during 2015-2016 in Hunan, China. Atmospheric Pollution Research, 2019, 10, 739-748.
[15] Hongli Huang, Lin Luo, Liuhui Huang, Jiachao Zhang, Petros Gikas, Yaoyu Zhou. Effect of Manure Compost on Distribution of Cu and Zn in Rhizosphere Soil and Heavy Metal Accumulation by Brassica juncea. Water Air Soil Pollution, 2020, 231, 195.
[16] Dongning Wei, Bingyu Li, Lin Luo, Yongxin Zheng, Liuhui Huang, Jiachao Zhang, Yuan Yang, Hongli Huang*. Simultaneous adsorption and oxidation of antimonite onto nano zero-valent iron sludge-based biochar: Indispensable role of reactive oxygen species and redox-active moieties. Journal of Hazardous Materials, 2020, 391: 122057.
[17] Dongning Wei, Bingyu Li, Hongli Huang*, Lin Luo, Jiachao Zhang, Yuan Yang, Jiajun Guo, Lin Tang, Guangming Zeng, Yaoyu Zhou. Biochar-based functional materials in the purification of agricultural wastewater: Fabrication, application and future research needs. Chemosphere, 2018, 197: 165-180.
[18] Shuang Luo, Liyuan Chai, Dionysios D. Dionysiou, Ruiyang Xiao, et al. Kinetic and mechanistic aspects of hydroxyl radical‒mediated degradation of naproxen and reaction intermediates. Water Research, 2018,137: 233-241. ESI高被引
[19] Shuang Luo, Ruiyang Xiao, Liyuan Chai, Dionysios D. Dionysiou, et al. Mechanistic insight into reactivity of sulfate radical with aromatic contaminants through single-electron transfer pathway. Chemical Engineering Journal, 2017, 327:1056–1065. ESI热点+高被引
[20] Shuang Luo, Ruiyang Xiao, Liyuan Chai, Dionysios D. Dionysiou, et al. UV direct photolysis of sulfamethoxazole and ibuprofen: An experimental and modelling study. Journal of Hazardous Materials, 2018, 343:132–139. ESI高被引
[21] Shuang Luo, Ruiyang Xiao, Liyuan Chai, et al. Quantitative structure‒activity relationships for reactivities of sulfate and hydroxyl radicals with aromatic contaminants through single‒electron transfer pathway. Journal of Hazardous Materials. 2018, 344:1165-1173. ESI高被引
[22] Shuang Luo, Ruiyang Xiao, Liyuan Chai, et al. A novel model to predict gas-phase hydroxyl radical oxidation kinetics of polychlorinated compounds. Chemosphere, 2017, 172: 333-340. ESI高被引
[23] Xie, X.; Cheng, H. A simple treatment method for phenylarsenic compounds: Oxidation by ferrate (VI) and simultaneous removal of the arsenate released with in situ formed Fe(III) oxide-hydroxide. Environment International, 2019, 127, 730.
[24] Xie, X.; Zhao, W.; Hu, Y.; Xu, X.; Cheng, H. Permanganate oxidation and ferric ion precipitation (KMnO4-Fe(III)) process for treating phenylarsenic compounds. Chemical Engineering Journal, 2019, 357, 600.
[25] Xie, X.; Hu, Y.; Cheng, H. Rapid degradation of p-arsanilic acid with simultaneous arsenic removal from aqueous solution using Fenton process. Water Research, 2016, 89, 59.
[26] Xie, X.; Hu, Y.; Cheng, H. Mechanism, kinetics, and pathways of self-sensitized sunlight photodegradation of phenylarsonic compounds. Water Research, 2016, 96, 136.
[27] Xie, X.; Zhang, Z.; Hu, Y.; Cheng, H. A mechanistic kinetic model for singlet oxygen mediated self-sensitized photo-oxidation of organic pollutants in water. Chemical Engineering Journal, 2018, 334 (Supplement C), 1242.
[28] Yan, B.H., Selvam, A., Wong, J. W., 2020. Bio-hydrogen and methane production from two-phase anaerobic digestion of food waste under the scheme of acidogenic off-gas reuse. Bioresource technology, 297, 122400.
[29] Waktole Berkessa Y., Yan, B. H.*, Li T. F., Jegatheesan J., Zhang Y. *, 2019.Treatment of anthraquinone dye textile wastewater using anaerobic dynamic membrane bioreactor: performance and microbial dynamics. Chemosphere, 238, 124539.
[30] Zhou, M. M., Yan, B. H.*, Lang, Q. L., Zhang, Y. * 2019. Elevated volatile fatty acids production through reuse of acidogenic off-gases during electro-fermentation. Science of the Total Environment, 668, 295-302.
[31] Waktole Berkessa Y., Yan, B. H.*, Li T. F., Tan M., She Z. L., Jegatheesan J., Jiang H.Q., Zhang Y. *, 2018. Novel anaerobic membrane bioreactor (AnMBR) design for wastewater treatment at long HRT and high solid concentration. Bioresource Technology, 250, 281-289.
[32] Yan, B. H., Selvam, A., Wong, J. W., 2017. Influence of acidogenic headspace pressure on methane production under schematic of diversion of acidogenic off-gas to methanogenic reactor. Bioresource Technology, 245, 1000-1007.
[33] Li Lei, Wang Qiang*, Yang Yuan*, Luo Li, Ding Ru, Yang Zhao-Guang, Li Hai-Pu. Extraction Method Development for Quantitative Detection of Silver Nanoparticles in Environmental Soils and Sediments by Single Particle Inductively Coupled Plasma Mass Spectrometry.Analytical Chemistry, 2019, 91(15), 9442-9450.
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六.国际合作与学术交流
项目团队依托的“湖南省农业典型污染物生态修复与实地保护国际科技合作基地”,是我省第一个(2018年)批准成立的以农业农村环境污染治理与湿地保护为工作核心的国际合作基地。基地建设探索开展“项目-人才-基地”相结合的国际科技合作模式,通过积极吸引汇聚国际创新力量和资源,集聚世界一流专家学者,合作培养国际化人才。能够有效地推动协同创新和开放创新,引领和支撑国家创新驱动发展战略实施,进一步扩大科技对外影响力,提升国际科技合作的质量和水平,并对我国农业面源污染防控、农业水资源安全利用、农业与矿山的可持续发展产生引领和示范效果。
项目团队通过与法国、菲律宾、澳大利亚、西班牙等国家开展深层次、多形式、全方位的科技合作,突破关键技术,积极吸收对方工程化、产业化的经验,重点攻克矿山酸性废水被动式生态处理、重金属面源污染生态拦截、农田养分高效利用、农田退水生态净化与回用等一批关键技术与装备,构建农业典型污染物(重金属、过量氮磷、农药)防控与修复技术体系,形成集成示范,建立相关技术规范与标准。
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